Sensitivity analysis of the results of kinetic modeling to the rate constants of the reaction steps
N. M. Baynazarova1, L. F. Nurislamova2, I. M. Gubaydullin3
|In mathematical modeling of chemical processes prime step isthe sensitivity analysis of the kinetic curves to the rate constants of steps. The analysis of the kinetic model sensitivity to variation of the rate constants of individual or all steps makes it possible to estimate the effect of a certain parameter on the function under consideration and differentiate between key parameters of the model and those that exert a negligible effect on the solution. Sensitivity analysis can be applied to reduce the system. The results of the local and global sensitivity analysis with respect to the oxidation of formaldehyde.
|kinetic model, oxidation reaction of formaldehyde, sensitivity analysis, reduction mechanism
1Graduate of the second year the Department of mathematical modelling, Bashkir State University, Ufa; Nurzilyasha@mail.ru.
2Second year postfraduate student, Institute of petrochemistry and catalysis of the Russian Academy of Sciences, Ufa; Nurislamova_LF@mail.ru.
3Senior Research Associate in the Laboratory of Mathematical Chemistry, Institute of petrochemistry and catalysis of the Russian Academy of Sciences, Ufa; IrekMars@mail.ru.
Citation: N. M. Baynazarova, L. F. Nurislamova, I. M. Gubaydullin, "[Sensitivity analysis of the results of kinetic modeling to the rate constants of the reaction steps]", Zhurnal Srednevolzhskogo matematicheskogo obshchestva,16:4 (2014) 23–32 (In Russian)